Hydrogen retention on pole-facing slopes

Lovelace (57.06 km; 82.08°N, 250.49°E) crater, of the Moon's far north, hosts a signature of volatiles within permanently shadowed regions (PSR) on the inside slope of its south wall. Long-term studies of the Moon's reserves of hydrogen and other volatiles, made possible by the extended science missions of the Lunar Reconnaissance Orbiter (LRO), show a diurnal cycle of hydrogen retention on pole-facing slopes, perhaps a result of neutral hydrogen from the Sun. [NASA/GSFC/ASU/LOLA/PDS].

Bill Steigerwald

Goddard Space Flight Center

Space travel is difficult and expensive – it would cost thousands of dollars to launch a bottle of water to the moon. The recent discovery of hydrogen-bearing molecules, possibly including water, on the Moon has explorers excited because these deposits could be mined if they are sufficiently abundant, sparing the considerable expense of bringing water from Earth.

Karnik

Lunar water could be used for drinking or its components – hydrogen and oxygen – could be used to manufacture important products on the surface that future visitors to the moon will need, like rocket fuel and breathable air.

Recent observations by NASA's Lunar Reconnaissance Orbiter (LRO) spacecraft indicate these deposits may be slightly more abundant on crater slopes in the southern hemisphere that face the lunar South Pole.

"There’s an average of about 23 parts-per-million-by-weight (ppmw) more hydrogen on Pole-Facing Slopes (PFS) than on Equator-Facing Slopes (EFS)," said Timothy McClanahan of NASA's Goddard Space Flight Center.

This is the first time a widespread geochemical difference in hydrogen abundance between PFS and EFS on the moon has been detected. It is equal to a one-percent difference in the neutron signal detected by LRO's Lunar Exploration Neutron Detector (LEND) instrument. McClanahan is lead author of a paper about this research published online October 19 in the journal Icarus.

The hydrogen-bearing material is volatile (easily vaporized), and may be in the form of water molecules (two hydrogen atoms bound to an oxygen atom) or hydroxyl molecules (an oxygen bound to a hydrogen) that are loosely bound to the lunar surface. The cause of the discrepancy between PFS and EFS may be similar to how the Sun mobilizes or redistributes frozen water from warmer to colder places on the surface of the Earth, according to McClanahan.

"Here in the northern hemisphere, if you go outside on a sunny day after a snowfall, you'll notice that there's more snow on north-facing slopes because they lose water at slower rates than the more sunlit south-facing slopes" said McClanahan. "We think a similar phenomenon is happening with the volatiles on the moon – PFS don't get as much sunlight as EFS, so this easily vaporized material stays longer and possibly accumulates to a greater extent on PFS."

The team observed the greater hydrogen abundance on PFS in the topography of the moon's southern hemisphere, beginning at between 50 and 60 degrees south latitude.

The Moon's polar south and its neutron suppression zpmes, indicative of the presence of hydrogen (inside and outside permanent shadow) mapped from data collected from the LRO LEND instrument over two and a half years [NASA/GSFC/SVS/Pockocmoc].

Slopes closer to the South Pole show a larger hydrogen concentration difference. Also, hydrogen was detected in greater concentrations on the larger PFS, about 45 ppmw near the poles. Spatially broader slopes provide more detectable signals than smaller slopes. The result indicates that PFS have greater hydrogen concentrations than their surrounding regions. Also, the LEND measurements over the larger EFS don't contrast with their surrounding regions, which indicates EFS have hydrogen concentrations that are equal to their surroundings, according to McClanahan. The team thinks more hydrogen may be found on PFS in northern hemisphere craters as well, but they are still gathering and analyzing LEND data for this region.

There are different possible sources for the hydrogen on the moon. Comets and some asteroids contain large amounts of water, and impacts by these objects may bring hydrogen to the moon. Hydrogen-bearing molecules could also be created on the lunar surface by interaction with the solar wind. The solar wind is a thin stream of gas that's constantly blown off the Sun. Most of it is hydrogen, and this hydrogen may interact with oxygen in silicate rock and dust on the moon to form hydroxyl and possibly water molecules. After these molecules arrive at the moon, it is thought they get energized by sunlight and then bounce across the lunar surface; and they get stuck, at least temporarily, in colder and more shadowy areas.

Since the 1960's scientists thought that only in permanently shadowed areas in craters near the lunar poles was it cold enough to accumulate this volatile material, but recent observations by a number of spacecraft, including LRO, suggest that hydrogen on the moon is more widespread.

It's uncertain if the hydrogen is abundant enough to economically mine. "The amounts we are detecting are still drier than the driest desert on Earth," said McClanahan. However, the resolution of the LEND instrument is greater than the size of most PFS, so smaller PFS slopes, perhaps approaching yards in size, may have significantly higher abundances, and indications are that the greatest hydrogen concentrations are within the permanently shaded regions, according to McClanahan.

The team made the observations using LRO's LEND instrument, which detects hydrogen by counting the number of subatomic particles called neutrons flying off the lunar surface. The neutrons are produced when the lunar surface gets bombarded by cosmic rays. Space is permeated by cosmic rays, which are high-speed particles produced by powerful events like flares on the Sun or exploding stars in deep space. Cosmic rays shatter atoms in material near the lunar surface, generating neutrons that bounce from atom to atom like a billiard ball. Some neutrons happen to bounce back into space where they can be counted by neutron detectors.

Neutrons from cosmic ray collisions have a wide range of speeds, and hydrogen atoms are most efficient at stopping neutrons in their medium speed range, called epithermal neutrons. Collisions with hydrogen atoms in the lunar regolith reduce the numbers of epithermal neutrons that fly into space. The more hydrogen present, the fewer epithermal neutrons the LEND detector will count.

Neutron suppression information in the Moon's polar north is, as yet, less granular than data mapped in greater detail over the far South. Here neutron suppression is overlaid on a LROC WAC mosaic with permanently shadowed regions (PSRs) outlined in black. Again, the occurrence of hydrogen is related to sunlight but not necessarily tied to its total absence.

The team interpreted a widespread decrease in the number of epithermal neutrons detected by LEND as a signal that hydrogen is present on PFS. They combined data from LEND with lunar topography and illumination maps derived from LRO's LOLA instrument (Lunar Orbiter Laser Altimeter), and temperature maps from LRO's Diviner instrument (Diviner Lunar Radiometer Experiment) to discover the greater hydrogen abundance and associated surface conditions on PFS.

In addition to seeing if the same pattern exists in the moon's northern hemisphere, the team wants to see if the hydrogen abundance changes with the transition from day to night. If so, it would substantiate existing evidence of a very active production and cycling of hydrogen on the lunar surface, according to McClanahan.

The research was funded by NASA's LRO mission. LEND was supplied by the Russian Federal Space Agency Roscosmos. Launched on June 18, 2009, LRO has collected a treasure trove of data with its seven powerful instruments, making an invaluable contribution to our knowledge about the moon. LRO is managed by NASA's Goddard Space Flight Center in Greenbelt, Maryland, for the Science Mission Directorate at NASA Headquarters in Washington.